欲配置pH=5.0的缓冲溶液,应选择的最佳缓冲对是 ( )
A: HAc-NaAc [pKa(HAc)=4.75]
B: NH3-NH4Cl [pKb(NH3)=4.75]
C: HCOOH-HCOONa [pKa(HCOOH)=3.75]
D: Na2HPO4-Na3PO4 [pKa3(H3PO4)=12.36]
A: HAc-NaAc [pKa(HAc)=4.75]
B: NH3-NH4Cl [pKb(NH3)=4.75]
C: HCOOH-HCOONa [pKa(HCOOH)=3.75]
D: Na2HPO4-Na3PO4 [pKa3(H3PO4)=12.36]
举一反三
- 欲配置pH=10的缓冲溶液,最好应选择的缓冲对是 A: HAc-NaAc[pKa(HAc)=4.75] B: NH3-NH4Cl[pKb(NH3)=4.75] C: HCOOH-HCOONa [pKa (HCOOH)=3.75] D: NaH2PO4-Na2HPO4 [pKa2(H3PO4)=7.2]
- 欲配制pH=3.5的缓冲溶液,应选择的缓冲对是() A: HCOOH(pKa=3.76)和HCOONa B: HPO(pKa1=2.16)和NaHPO C: NHCl和NH(pKb=4.75) D: HAc(pKa=4.75)和NaAc
- 欲配制pH=10的缓冲溶液,应选用( )缓冲对。 A: HCOOH-HCOONa [pKa⊙(HCOOH) = 3.75] B: HAc-NaAc [pKa⊙(HAc) = 4.74] C: NaH2PO4- Na2HPO4 [pKa2⊙(H3 PO4) = 7.21] D: NH3-NH4Cl [pKb⊙(NH3) = 4.75]
- 欲配制pH=3.5的缓冲溶液,应选择的缓冲对是() A: HCOOH(pKa=3.76)和HCOONa B: H3PO4(pKa1=2.16)和NaH2PO4 C: NH4Cl和NH3(pKb=4.75) D: HAc(pKa=4.75)和NaAc
- 现要配制pH=4.5的缓冲溶液,最理想的缓冲对是()。 A: ANaH<sub>2</sub>PO<sub>4</sub>-Na<sub>2</sub>HPO<sub>4</sub>(pK(H<sub>2</sub>PO<sub>4<sup><sup>-</sup>)=7.21)</sup></sub> B: BHAc-NaAc(pK(HAc)=4.76) C: CHCOOH-HCOONa(pK(HCOOH)=3.75) D: DNH<sub>3</sub>-NH<sub>4</sub>Cl(pK(NH<sub>3</sub>)=4.75)