• 2022-07-24
    根据锰元素的标准电势图讨论以下问题:[tex=1.143x1.357]VAHhaW1te0xvoqDVN54/dg==[/tex]根据[tex=3.714x1.357]h38jiy/Ai9WA7tRoW0XEVg==[/tex]的歧化反应设计原电池, 并计算电池的标准电动势和[tex=3.714x1.357]h38jiy/Ai9WA7tRoW0XEVg==[/tex]歧化 反应的标准平衡常数; [tex=1.286x1.357]GEp98LAjkJwaCSrpbBogIw==[/tex] 通过计算说明[tex=3.643x1.429]KzT/d5Rdg8SKcjZlyK4Pbg26T75H8M7v128WtCeHajE=[/tex]离子稳定存在的 [tex=1.357x1.214]CivFLwz+h83nxauABgw/KQ==[/tex]最低为多少?
  • 答:锰元素的标准电势图如下:[img=573x189]17a38ab30c21891.png[/img][tex=1.286x1.357]VAHhaW1te0xvoqDVN54/dg==[/tex] 在酸性介质中[tex=3.714x1.357]h38jiy/Ai9WA7tRoW0XEVg==[/tex] 的歧化反应式为:[tex=33.286x5.929]qeiYnKXLEhyhuGRg8yLtrxW/V94FYL1bv6Ym3KO9va/eiKApO/Mu+M/JcXTSvT/ih9pWIagPu+K/qVaOys52aujIZ8dqIOW34alGiqds9thg8Sitgkrrp369L3Wo9v36KlueqYHJ4aFczRuhSQeDXlAOvi8zbveQyJmdycqLEUL449l1OR2vAHBXXZxBftI+9ghxSTpAaDU5x/UYIMNZ5Dn3ZoS38gdqZe78vp0NFxCS3fSaY/s7SNNqz83hVLItQ3mbe7Ig71xZ+864o+aQeN+oQk7mF/DYZAlx+Nn4Q3SKeD8ZuZ2itg4W+RRE1rBHGeIc2xn5853tAYTC8hHzNqXmA1SN5NuPfJdXeg7IR1XjWGqjqd1sViVK3pkAloLZEpIhmV9lKNoVOH3c/N9gmqzQ7d64dA5ML0sVHMUmZEQqJnvPDYxiDi4H3UsYvwA/Qje+y/uBoXxObrJJ55DNmjb3oFV7d5LDV/OQ9lfDz0o=[/tex][tex=6.214x1.357]lldefEcFT2cbwJZ5bzpE5GSHBzyQkNdpJ3y2c7/zLkk=[/tex]在碱性介质中[tex=3.714x1.357]h38jiy/Ai9WA7tRoW0XEVg==[/tex]歧化反应式为:[tex=39.143x7.214]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[/tex]由计算可知, 无论在酸性介质还是在碱性介质中, [tex=3.714x1.357]h38jiy/Ai9WA7tRoW0XEVg==[/tex] 都有发生歧化反应趋势, 且在酸性介质中, [tex=3.714x1.357]h38jiy/Ai9WA7tRoW0XEVg==[/tex] 歧化反应进行的趋势更大。[tex=1.286x1.357]BEB68bP4vOVk/XYYizw11w==[/tex] 由针元素的标准电势图可知, 在碱性介质中, 标准条件下 [tex=3.643x1.429]KzT/d5Rdg8SKcjZlyK4Pbg26T75H8M7v128WtCeHajE=[/tex]仍可发生如下歧化反应:[tex=18.286x1.5]mme6P4PI1lcLrHtaqpRHdZ0Q3l5sZJx7jAwJATmyQ0AMeAf2xmgMFKBrFaBXjve3ahvY5o7SgCpWtRXBofaGuE7YT9MYehYqiFWvpdA3eNE=[/tex]若要[tex=3.643x1.429]KzT/d5Rdg8SKcjZlyK4Pbg26T75H8M7v128WtCeHajE=[/tex]稳定存在, 则该歧化反应的 [tex=3.5x1.357]qfgqEKEXRp2EoR9TnIg7WoxxDPhsu4ulKeG4cHp6M6Y=[/tex] 即 [tex=12.357x1.571]WZRKbaqTKcrY+jxcEBr5bao3pvAZYNMy97bvgYHDcahR8X7SmVZp/s+V36SV8oMp4CA2uoV+dWwIIKCwxqditA==[/tex]则有[tex=15.571x1.5]STT7UHBDgcMUOazygbNCnw46MWorx1aCxLzPIkNG9scl4CDWmV6gVfhbQvvsXtOUixcY5Tq/CpccXkK893fxYw==[/tex][tex=31.429x3.071]WZRKbaqTKcrY+jxcEBr5bSYptA2DaunfD4r5bZ+wMfMeDSy8nwv2ol1mvEiklGhSaG74zaNqXKLsK7xw1LaFnkoHdVF4HMqFDxEVHkq+DJbE/vbrEDXGduF83gExyo5RkhYSonetN06dhND4SDJxy6FRsuMNiJ1QA4T6ml/Yvm2H8g/7RRDIRMMaT5aA/8Y486ta7EfLufIpKyJlK7yT+AJthj9ijO0E3oARPTMmxNETgXD71pLcQ+L4E6wveoAI[/tex]即 [tex=15.929x3.071]THJB6yqH1tD+tMay3OVrBjJp4aduLs+IMl+sw7i54b0BcHF6g3Qj3EMjMwm/guL6WQrKp6DVjpDZMDaG7tEZl4Tor9ZARRGImOBykRJVVTTC4olhXtYSF4kmIU9qRWkRsqGfzgiWg04ZUOWaoRSlHg==[/tex]设[tex=9.071x1.571]oqJpwjA7a/Zg3aKlxC2FT8Gtb74RuinnS5ppVRlcpL6czB1ftmogDDtujULQo6Yz[/tex]解得[tex=8.571x1.5]QgamVD3fhGHY0kFaEpuVekjjCzTgS6+Q0I/nfPpGlNpLv7NIt+cP9LV7R7UQokJW[/tex]故[tex=13.5x1.571]KzT/d5Rdg8SKcjZlyK4PbvrfDc9V8YUcOQANU5NxkdENq1/MzvZPOT2rXKEntiIVzmcZ/AsMMhsrL6xuouCsCdN04ZCnsa5y2hRgJVo++nc=[/tex]稳定存在的条件是溶液的 [tex=3.143x1.5]QgamVD3fhGHY0kFaEpuVep+hBS6DJvnJTKO+6+8NiHg=[/tex]不得低于 [tex=4.143x1.357]PNVjpfYrRU3XtZtBAOi7vw==[/tex] 。

    举一反三

    内容

    • 0

      若:(1)函数 f(x)在点[tex=3.714x1.357]7VByCIzkNySq3s2l9I6f5zccNJDeV+6SQrVr3iwjgB0=[/tex]有导数,而函数g(x)在点[tex=2.286x1.0]DSJKaWfJALImFxxTg/8qhA==[/tex]没有导数;(2)函数f(x)在点[tex=3.714x1.357]7VByCIzkNySq3s2l9I6f5zccNJDeV+6SQrVr3iwjgB0=[/tex]没有导数,而函数g(x)在点[tex=2.286x1.0]DSJKaWfJALImFxxTg/8qhA==[/tex]有导数;(3)函数f(x)在点[tex=3.714x1.357]7VByCIzkNySq3s2l9I6f5zccNJDeV+6SQrVr3iwjgB0=[/tex]没有导数及函数g(x)在点[tex=2.286x1.0]DSJKaWfJALImFxxTg/8qhA==[/tex]没有导数,则函数[tex=5.643x1.357]GmtX7Vop79exGU/rpqXUYw==[/tex]在已知点[tex=2.286x1.0]DSJKaWfJALImFxxTg/8qhA==[/tex]的可微性怎样?

    • 1

      [tex=14.929x2.571]fkMbnACOf8CCcXOh6WscF5FDDmK29PsjMPGgk8Fzc+qTmCnbdf6Hh66ys1PM33IqnUFiqHHN2AtOOq0agCfJp4Q/tyc3CjIyMe9gJI/XS1sxjCsFmjEJIqvPiuv4qnPn[/tex][br][/br]根据上面给出的部分 [tex=1.214x1.0]qScDTLoY/UqqN5O0RS2MRg==[/tex]的元素电势图,计算下列各原电池的电动势 [tex=1.429x1.143]NTcnehKtV1eJ8uwiBPjiww==[/tex] 及其电池反应的 [tex=2.571x1.429]FfvUS6LSan93KcaOqKhmpIO05Yc2y2drpDJEfLHXKRc=[/tex]。[br][/br][tex=8.143x1.571]qbwE4oLnQvNnKVgb629ncUW0qZ0+cEh9bRBNDhDatjthRv0H86fs/boqsCBU0YJf[/tex]

    • 2

      [tex=14.929x2.571]fkMbnACOf8CCcXOh6WscF5FDDmK29PsjMPGgk8Fzc+qTmCnbdf6Hh66ys1PM33IqnUFiqHHN2AtOOq0agCfJp4Q/tyc3CjIyMe9gJI/XS1sxjCsFmjEJIqvPiuv4qnPn[/tex][br][/br]根据上面给出的部分 [tex=1.214x1.0]qScDTLoY/UqqN5O0RS2MRg==[/tex]的元素电势图,计算下列各原电池的电动势 [tex=1.429x1.143]NTcnehKtV1eJ8uwiBPjiww==[/tex] 及其电池反应的 [tex=2.571x1.429]FfvUS6LSan93KcaOqKhmpIO05Yc2y2drpDJEfLHXKRc=[/tex]。[br][/br][tex=10.357x1.571]6K2ycvTPLtn0PjfI2VvQ/O7sgBYXYRb2gaJR3xdwzWGkcKWYk5oDLeMbROg6x+WFZO6l28YJNxGpeuY1Kmcmqg==[/tex]

    • 3

      某甲的效用函数为[tex=7.429x1.357]/H5u445kuYBH+5SQt0CL1P8CB2hEEOC1mrvGUIA5btw=[/tex],x、y是商品X、Y的消费量。X、Y的价格分别为[tex=1.286x1.214]fAqzCb4JfIb9dcRelloMyw==[/tex]和[tex=1.071x1.214]H/unJ0FK97BmBl+YVZimWA==[/tex]证明如果某甲两种商品都购买,那么其消费量[tex=2.286x1.357]31CzVDPWEEnJrSJJlGK6fQ==[/tex]满足[tex=8.214x1.357]Bs04DFyOaNf4jvtaHT9Nbs35SFrWHKY+AJirYNNlVcw=[/tex]

    • 4

      于标准状态时,用电对[tex=3.5x1.5]QwxNl0iwS1FbwRw8f5Rk8RAvwW5VSGbEB0eTGVa5LMU=[/tex]和[tex=3.929x1.5]W+OwdacWFJneQo0l/K1QJq2M0+vRqRn6uvmOtENGRQM=[/tex]组成电池:计算电池电动势,电池反应的标准吉布斯能和平衡常数。