• 2022-07-26
    氢气在锌电极上的超电势 [tex=0.5x1.0]x1bygMLZjErpcp7AR7KkLQ==[/tex] 与电极上通过的电流密度[tex=1.0x1.357]enHqTEBqFuqXT6sgHJDhSebjUX1FGhpVgJ6c2WLDLDU=[/tex] 单位为[tex=3.714x1.5]iH27PNnlqF9JSfa0olTmek2E4+xz3dnb/Bexa2L5xAw=[/tex]的关系为[tex=13.714x1.571]lh3mrjJC7Zu5ntHnm6PCLASp4eWFy2LAHElIpWK6m41dKjBZn7C+6crHsqEs2AkCvu/wrng0cbo/4X7Z8ttKSqFGgYdSSAFWAVznatc69dA=[/tex]在 [tex=2.357x1.0]/NnQehdlK2QR+QNALFVBUw==[/tex] 时,用 [tex=1.286x1.0]sGznpqmCsEc+mJe3hXIkxA==[/tex] 作阴极,惰性物质作阳极,电解液依度为 [tex=5.214x1.429]e71xu/DWDGIKzbYTIXwoxnmShXLkYZqkh8+Kgs4Ubms=[/tex] 的 [tex=3.071x1.214]BjjYsuZZ36o2ncg4gaLEww==[/tex] 溶液,设[tex=1.357x1.214]CivFLwz+h83nxauABgw/KQ==[/tex]为[tex=0.5x1.0]+ElP8Glp1jNyDFWBiVUf/g==[/tex] 。若要使 [tex=2.5x1.357]XvDJ2mVHQ/AZbbT714QswQ==[/tex] 不与[tex=1.286x1.0]sGznpqmCsEc+mJe3hXIkxA==[/tex]同时析出,应控制电流密度在什么范围内? [提示:注意分析超电势使氢电极电势增大还是减小。]
  • 解     [tex=1.286x1.0]sGznpqmCsEc+mJe3hXIkxA==[/tex] 作阴极,电解浓度为 [tex=12.929x1.571]e71xu/DWDGIKzbYTIXwoxmsk/2uy0YbOcBQmgcR7V3cZVLZ4SAxb3hEbLdhU9B7RB1gy/qDSDnQ2VK36nnZyjJ9tp0ZPhgacDvPaDIzC00E=[/tex] 的 [tex=3.071x1.214]BjjYsuZZ36o2ncg4gaLEww==[/tex]溶液,阴极可能发生的反应为[tex=6.643x1.357]d0Lp6nGEzyqHNxCcpWt96hSlrcM5cXqYJj+LQNm/NhU=[/tex][tex=6.286x1.357]pvRHhB1uhdVc4QKQxQRjcdHcP9pRSePqJPt3QXcd+lE=[/tex][tex=1.286x1.0]cLf1+ueR+iiGFyk14tV/sA==[/tex] 的析出电势为[tex=24.786x2.429]umThn9lR5lvluSlKzYyxkQ5Fk0gignmAMbzgkUX5EJ/+FjbzlKRr2te2enJJcWfJ0a2/qE+Rspy2czTOGXjdJi6tMXJsr+mQg+cmOlEBBGoEcAkOxWLjhU9GghP6tjnI0fqPqE1Wons08Dq7/KH0RvTjpjYwkHh5LqnA8KYEwE9xDuPEfU+oR1szgWjq0P2m7zVtDEz6OpDb2a2ZpLyUhQ==[/tex][tex=12.357x2.429]cjqYpZnCGOGz63sgaEUgLtCQfXqv9rwzgITiL1mxp1FO16GfvIBpALh7dJQsPZUD[/tex][tex=17.286x2.429]cjqYpZnCGOGz63sgaEUgLtCQfXqv9rwzgITiL1mxp1Ebqd+iBRI00xKuV/AQM0pUEnBZnNOUK/mQiCebXmk6OQ==[/tex][tex=1.214x1.214]lAUWqU1sTBzI68Pw72NaYA==[/tex] 的析出电势 [tex=5.5x1.5]e1ey2wYbF+iC00uduNl8ZmooKh4PiW+KQVy1pf7FJT0PTpfMoFcAFI1o/ogV4jVxe2klPyHxgxHDDba2+OlStQ==[/tex]为[tex=27.714x2.0]xEX68knBjCanG8GoK/8Zlfl5mSnelzvtfflMUoWlCFue6Ki3hoEY/fI/XvGzfN+TxeyERYaFLnzJyA+r6QjZ4PMOj9S8tLtrdpH0ViAj+S5+A6Zf224xxzITIsrG63LYBdwWYZOpawtazo6ecsbfCRo0Q80HUcI0efli9fsQYHuWN43FdiNGcj4UeAtRvWmrbxnQuholOikPDNkjPw9s5Wen4066XHSBspXecqI+18c=[/tex][tex=12.5x1.286]gWbXBjMCx37nD7lT8eYe08UIi2SIeQbHz4v033Uurh/AemI6gUcwFjEmoUpRBJw7[/tex][tex=8.643x1.286]GOaPi+oaq1NcXwehDFCb9Kh8FVBcjU8VYeajHy/vNYg=[/tex]为使 [tex=2.5x1.357]XvDJ2mVHQ/AZbbT714QswQ==[/tex] 与 [tex=1.286x1.0]sGznpqmCsEc+mJe3hXIkxA==[/tex] 不同时析出,即[tex=1.286x1.0]sGznpqmCsEc+mJe3hXIkxA==[/tex] 析出, [tex=2.5x1.357]XvDJ2mVHQ/AZbbT714QswQ==[/tex] 不析出,则要求[tex=25.286x1.286]xEX68knBjCanG8GoK/8ZlQpIP4FJl+F8vIeqd5tYxS1OimgHrLTGbNKD1omX9Qt6Mf0/wFnNxaIgi4USxDQT5AWsPSy+rLb92gpn47DfC5qJwCnbO0EcZdINzZw23cAi8PTHMrp/rCfGTfoQybHTCQ==[/tex][br][/br][tex=7.071x1.286]VpZ1sucI/A77VsPWD0qXDncrkEk+rxyrY0SqhgTCjlQ=[/tex]又因为 [tex=12.929x1.214]4jwdgRj3UqaBWRYM4/5cDML6oL7uZl//iOPF67wiIGBtjoeywIvkciHu4m0Lh7xn[/tex]所以 [tex=9.5x1.429]Zcq/AGBNFt44l18BlHNluEoyDZr5EieBwx4HxwZobyB7ADNLTg7oRXLMwWuOPr4T[/tex]即应控制电流密度大于[tex=7.714x1.357]jgoAPJsUHaqQhGkIjP/rtwDtnZym/J0GYjJqsYXu7OR7ySZ2DvLw8rlejIiS05CE[/tex] 。

    举一反三

    内容

    • 0

      若:(1)函数 f(x)在点[tex=3.714x1.357]7VByCIzkNySq3s2l9I6f5zccNJDeV+6SQrVr3iwjgB0=[/tex]有导数,而函数g(x)在点[tex=2.286x1.0]DSJKaWfJALImFxxTg/8qhA==[/tex]没有导数;(2)函数f(x)在点[tex=3.714x1.357]7VByCIzkNySq3s2l9I6f5zccNJDeV+6SQrVr3iwjgB0=[/tex]没有导数,而函数g(x)在点[tex=2.286x1.0]DSJKaWfJALImFxxTg/8qhA==[/tex]有导数;(3)函数f(x)在点[tex=3.714x1.357]7VByCIzkNySq3s2l9I6f5zccNJDeV+6SQrVr3iwjgB0=[/tex]没有导数及函数g(x)在点[tex=2.286x1.0]DSJKaWfJALImFxxTg/8qhA==[/tex]没有导数,则函数[tex=5.643x1.357]GmtX7Vop79exGU/rpqXUYw==[/tex]在已知点[tex=2.286x1.0]DSJKaWfJALImFxxTg/8qhA==[/tex]的可微性怎样?

    • 1

      设h为X上函数,证明下列两个条件等价,(1)h为一单射(2)对任意X上的函数[tex=5.429x1.214]3BrfPgAFe5dbHQTMAYnbS+118W4YAj6CiW06EKMaxNI=[/tex]蕴涵[tex=1.786x1.214]pxzkG5OdsKT9CiCwC5OvPQ==[/tex]

    • 2

      若氢在[tex=1.286x1.0]VF8+1TzmsJRetv2yOm9c4g==[/tex]、[tex=1.357x1.214]oQu90KoPcZ1jfjH4MlgbLA==[/tex]电极上的超电势在所讨论的电流密度范围内服从塔菲尔公式[tex=5.143x1.214]lzlb+CCvC8nDX6gn1A9kfA==[/tex]。对于上述两电极[tex=0.429x1.0]JThLUuJ8WswSAPiYZWihWg==[/tex]均为[tex=3.071x1.0]hh7RekLljqhR22a0Xu7Riw==[/tex],但二者的[tex=0.571x0.786]c59+3vo0/Vn/FvNRhDRu5g==[/tex]不同。氢在这些电极上析出的传递系数[tex=0.643x0.786]SPoVA3bJlgfP9Ek9O4AbuA==[/tex]均为0.5,电极反应得失电子数均为1。氢在[tex=1.286x1.0]VF8+1TzmsJRetv2yOm9c4g==[/tex]和[tex=1.357x1.214]oQu90KoPcZ1jfjH4MlgbLA==[/tex]上的交换电流[tex=0.929x1.214]6SP1pOd/CUBuehFJlkNo+Q==[/tex]分别是[tex=7.0x1.357]iFGgafcuz9Z7Ouz/Y0W4LTEi/HM5xChiSp8fDLS0qDs=[/tex]和[tex=7.0x1.357]IzP9ZZRkZnbQNAwKGJbNleUJi2aWSswphb7AC1KhNZA=[/tex]。求在[tex=2.357x1.0]m5fKCA0WGhfJpuVc0VWfdw==[/tex]时二电极通过相同的电流密度情况下,氢在[tex=1.357x1.214]oQu90KoPcZ1jfjH4MlgbLA==[/tex]、[tex=1.286x1.0]VF8+1TzmsJRetv2yOm9c4g==[/tex]两电极上的超电势的差值。

    • 3

      判断下列命题是否为真:(1)[tex=3.643x1.357]/5abqJjwKZ1qr+6hsVFF5EBvfq3ggOFNlHMClz0h9nk=[/tex](2)[tex=2.929x1.357]rGJpyjIjJpbcoBTWxP0Jiw==[/tex](3)[tex=4.5x1.357]2wycHMoqU83MyEp17iBils58bR7YLuCTI2G9NVAdlfY=[/tex](4)[tex=5.214x1.357]CTz2gu+IIm1GgNmYMGaduCRtA41wnW4WqwRWwEhq6aA=[/tex](5)[tex=4.857x1.357]1DcE2BMMOaZhTuxR/mjgsboXxfg5ET59Dp4I/jjEDuw=[/tex](6)[tex=4.643x1.357]BSryrsQYOvTP2hTWRu6t4nAuJwlSs4L9jaq70EpB+Us=[/tex](7)若[tex=6.0x1.357]y0IZLUnBO88nR8WBZYvd7QXv5S1OMINV5cQNzPyiyAc=[/tex],则[tex=3.429x1.357]1brfPwTkVVIX4GfoMIUskA==[/tex](8)若[tex=7.643x1.357]MhLfJXZnhbXiB0x3oNtFzThV4Y1mJxe1VYr7PkJE/T6hmTD3WWp+UxbNwvUQ6DHk[/tex],则[tex=4.143x1.357]LZUA94ISo1po5HWsOVeBCjo0rMvj7uw3bGw5HiZenrI=[/tex]

    • 4

      若:(1)函数 f(x)在点[tex=0.929x1.0]cjoIbYuE/p4IqfLA8eA4ZA==[/tex]有导数,而函数g(x)在此点没有导数;(2)函数f(x)和g(x)二者在点[tex=0.929x1.0]cjoIbYuE/p4IqfLA8eA4ZA==[/tex]都没有导数,可否断定它们的和[tex=7.214x1.357]oX568MWmpJJk2c1dN8FEzQ==[/tex]在点[tex=2.286x1.0]DSJKaWfJALImFxxTg/8qhA==[/tex]没有导数?